When you install Joomla 2.5 on your website, an administrator account is created by default. If someone else needs to manage the website. Create a new administrator is very easy. The Following steps will guide you how.

1. Log into Joomla 2.5 dashboard:
2. Right in the top menu, go to Users then Users Manager and click Add New User: 
3. Adds the information requested in Account Details, as shown below: 
4. Now, just Assigned User Group by marking the box Super Users, and then click Save: 

And that’s it! You just create a new administrator to your website joomla 2.5.
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